Assign a workflow to a template
The best way to assign a workflow to a template is through its __Standard Values definition item:
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Click the /sitecore/Templates/Sample/Sample template and then its
__Standard Valuesdefinition item.
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Click the View tab, the View group, and select the Standard Fields checkbox.

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Click the Workflow section, the Default workflow field, and select the Product Review workflow. Remember to save the changes.

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Content items using the Sample template now adheres to the Product Review workflow.
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